20 Dec 2023

Graphene in Cementitious Materials

Abstract: This project aims to determine the influence of laboratory-generated graphene (LGG) and commercial-grade graphene (CGG) on the chemical structure and compressive strength of graphene-cement mixtures. Determining the graphene-cement structure/processing/property relationships provides the most useful information for attaining the highest compressive strength. Graphene dose and particle size, speed of mixing, and dispersant agent were found to have important roles in graphene dispersion by affecting the adhesion forces between calcium silicate hydrate (CSH) gels and graphene surfaces that result in the enhanced strength of cement-graphene mixtures. X-ray diffraction (XRD), Raman, and scanning electron microscope (SEM) analyses were used to determine chemical microstructure, and compression testing for mechanical properties characterization, respectively. Based on observed results both LGG and CGG graphene cement mixtures showed an increase in the compressive strength over 7-, 14-, and 28-day age curing periods. Preliminary dispersion studies were performed to determine the most effective surfactant for graphene dispersion. Future studies will continue to research graphene—cement mortar and graphene—concrete composites using the most feasible graphene materials. These studies will prove invaluable for military programs, warfighter support, climate change, and civil works.

15 Dec 2023

Ranking Ports by Vessel Demand for Depth

Abstract: The US Army Corps of Engineers (USACE) traditionally uses two metrics to evaluate the maintenance of coastal navigation projects: tonnage at the associated port (representing relative importance) and the controlling depth in the channel (representing operating condition). These are incorporated into a risk-based decision framework directing funds where channel conditions have deteriorated and the disrupted tonnage potential is the highest. However, these metrics fail to capture shipper demand for the maintained depth service provided by the USACE through dredging. Using automatic identification system (AIS) data, the USACE is pioneering new metrics describing vessel demand for the channel depth, represented by vessel encroachment volume (VEV). VEV describes the volume of the hull intruding into a specified clearance margin above the bed and captures how much vessels use the deepest portions of USACE-dredged channels. This study compares the VEV among 13 ports over 4 years by combining AIS, tidal elevations, channel surveys, and sailing draft. The ports are ranked based on the services demanded by their user base to inform the decision framework driving dredge funding allocations. Integrating demand for-depth metrics into the Harbor Maintenance Fee assessment and/or Trust Fund disbursements could alleviate the constitutionality concerns and several criticisms levied against Harbor Maintenance funding.

15 Dec 2023

Challenges and Limitations of Using Autonomous Instrumentation for Measuring In Situ Soil Respiration in a Subarctic Boreal Forest in Alaska, USA

Abstract: Subarctic and Arctic environments are sensitive to warming temperatures due to climate change. As soils warm, soil microorganisms break down carbon and release greenhouse gases such as methane (CH4) and carbon dioxide (CO2). Recent studies examining CO2 efflux note heterogeneity of microbial activity across the landscape. To better understand carbon dynamics, our team developed a predictive model, Dynamic Representation of Terrestrial Soil Predictions of Organisms’ Response to the Environment (DRTSPORE), to estimate CO2 efflux based on soil temperature and moisture estimates. The goal of this work was to acquire respiration rates from a boreal forest located near the town of Fairbanks, Alaska, and to provide in situ measurements for the future validation effort of the DRTSPORE model estimates of CO2 efflux in cold climates. Results show that soil temperature and seasonal soil thaw depth had the greatest impact on soil respiration. However, the instrumentation deployed significantly altered the soil temperature, moisture, and seasonal thaw depth at the survey site and very likely the soil respiration rates. These findings are important to better understand the challenges and limitations associated with the in situ data collection used for carbon efflux modeling and for estimating soil microbial activity in cold environments.