12 Jul 2022

Boronic Acid Functionalized Ferrocene Derivatives Towards Fluoride Sensing

Abstract: In this technical report (TR), a robust, readily synthesized molecule with a ferrocene core appended with one or two boronic acid moieties was designed, synthesized, and used toward F- (free fluoride) detection. Through Lewis acid-base interactions, the boronic acid derivatives are capable of binding with F- in an aqueous solution via ligand exchange reaction and is specific to fluoride ion. Fluoride binding to ferrocene causes significant changes in fluorescence or electrochemical responses that can be monitored with field-portable instrumentation at concentrations below the WHO recommended limit. The F- binding interaction was further monitored via proton nuclear magnetic resonance spectroscopy (1H-NMR). In addition, fluorescent spectroscopy of the boronic acid moiety and electrochemical monitoring of the ferrocene moiety will allow detection and estimation of F- concentration precisely in a solution matrix. The current work shows lower detection limit (LOD) of ~15 µM (285 μg/L) which is below the WHO standards. Preliminary computational calculations showed the boronic acid moieties attached to the ferrocene core interacted with the fluoride ion. Also, the ionization diagrams indicate the amides and the boronic acid groups can be ionized forming strong ionic interactions with fluoride ions in addition to hydrogen bonding interactions.

31 Mar 2022

Design, Construction, and Testing of the PFAS Effluent Treatment System (PETS), a Mobile Ion Exchange–Based System for the Treatment of Per-, Poly-Fluorinated Alkyl Substances (PFAS) Contaminated Water

Abstract: Poly-,Per-fluorinated alkyl substances (PFAS) are versatile chemicals that were incorporated in a wide range of products. One of their most important use was in aqueous film-forming foams for fighting liquid fuel fires. PFAS compounds have recently been identified as potential environmental contaminants. In the United States there are hundreds of potential military sites with PFAS contamination.The ERDC designed and constructed a mobile treatment system to address small sites (250,000 gallons or less) and as a platform to field test new adsorptive media. The PFAS Effluent Treatment System (PETS) has cartridge filters to remove sediments and a granular activated carbon (GAC) media filter to remove organic compounds that might compete with PFAS in the ion exchange process, although it may also remove PFAS too. The last process is an ion exchange resin specifically designed to remove PFAS to a target level of 70 ng/L or less (equivalent to the US Environmental Protection Agency (EPA) Drinking Water Health Advisory). The system was tested at Hurlburt Field, a US Air Force facility in Florida and at Naval Support Activity (NSA) Mid-South in Millington, TN.

9 Dec 2021

Evaluation of Geocell-Reinforced Backfill for Airfield Pavement Repair

Abstract: After an airfield has been attacked, temporary airfield pavement repairs should be accomplished quickly to restore flight operations. Often, the repairs are made with inadequate materials and insufficient manpower due to limited available resources. Legacy airfield damage repair (ADR) methods for repairing bomb damage consist of using bomb damage debris to fill the crater, followed by placement of crushed stone or rapid-setting flowable fill backfill with a foreign object debris (FOD) cover. While these backfill methods have provided successful results, they are heavily dependent on specific material and equipment resources that are not always readily available. Under emergency conditions, it is desirable to reduce the logistical burden while providing a suitable repair, especially in areas with weak subgrades. Geocells are cellular confinement systems of interconnected cells that can be used to reinforce geotechnical materials. The primary benefit of geocells is that lower quality backfill materials can be used instead of crushed stone to provide a temporary repair. This report summarizes a series of laboratory and field experiments performed to evaluate different geocell materials and geometries in combinations with a variety of soils to verify their effectiveness at supporting heavy aircraft loads. Results provide specific recommendations for using geocell technology for backfill reinforcement for emergency airfield repairs.

1 Dec 2021

Development of Smartphone-Based Semi-Prepared Runway Operations (SPRO) Models and Methods

Abstract: The U.S. Army Engineer Research and Development Center (ERDC) has developed a method for predicting surface friction response by use of ground vehicles equipped with deceleration-based measurement devices. Specifically, the ERDC has developed models and measurement methods between the Findlay Irvine Mk2 GripTester and a variety of deceleration measurement devices: Bowmonk AFM2 Mk3, Xsens MTi-G-710, two Android smartphones, and two iOS smartphones. These models show positive correlation between ground vehicle deceleration and fixed-slip surface continuous surface friction measurement. This effort extends prior work conducted by the U.S. Army ERDC in developing highly correlative models between the Findlay Irvine Mk2 GripTester and actual C-17 braking deceleration, measured via the runway condition rating (RCR) system. The models and measurement methods detailed here are of considerable use to semi-prepared airfield managers around the world needing to measure safe landing conditions following inclement weather. This work provides the tools necessary for airfield managers to quantify safe landing conditions for C-17 aircraft by using easily obtainable equipment and simple test standards.

18 Nov 2021

Demonstration of Subsurface Passive Acoustic Monitoring (SPAM) to Survey for and Estimate Populations of Imperiled Underwater-calling Frogs

Abstract: The management and recovery of threatened and endangered amphibians on Department of Defense (DoD) lands relies on an understanding of their distribution and abundance. Fortunately, most anuran species can be surveyed acoustically using vocalizations during the breeding season. This work demonstrated the use of subsurface passive acoustic monitoring (SPAM) to survey for rare underwater-calling, at-risk anuran species on DoD installations. We evaluated the performance of SPAM relative to traditional passive acoustic monitoring (PAM) (microphone) and human manual calling survey (MCS) methods. Results showed that SPAM outperformed PAM and MCS in validation experiments where calls were generated underwater; SPAM was less successful than PAM and MCS in the field demonstration. Most leopard frog calls were apparently produced in air despite previous reports of extensive underwater-calling behavior. This project highlights how acoustic information can help address a data gap in the ecology of at-risk species, which can help refine future survey methodology and management efforts. Ultimately, the utility of SPAM for underwater-calling species will depend on the focal species, the landscape where it occurs, and technological considerations available to the surveyor. SPAM is more expensive than traditional methods but, in some situations, may be the only way to effectively detect species.

13 Oct 2021

Engineering With Nature®: Supporting Mission Resilience and Infrastructure Value at Department of Defense Installations

Abstract: This book illustrates some of the current challenges and hazards experienced by military installations, and the content highlights activities at seven military installations to achieve increased resilience through natural infrastructure.

29 Sep 2021

Threatened, Endangered, and At-Risk Species for Consideration into Climate Change Models in the Northeast

Abstract: This special report provides a selection process for choosing priority species using the specific focus of high-elevation, forested habitats in the North Atlantic to demonstrate the process. This process includes criteria for choosing invasive species to incorporate into models, given the predicted spread of invasive plant species because of climate change. Discussed in this report are the US Army Corps of Engineers’ Threatened and Endangered Species Team portal, the US Fish and Wildlife Service’s Information for Planning and Consultation Portal, the nonprofit organization Partners in Flight’s watch list, the US Geological Survey’s Biodiversity Information Serving Our Nation model, and NatureServe’s interagency effort Landfire. The data linked this montane habitat with a species of conservation concern, Cartharus bicknelli and the endangered squirrel Glaucomys sabrinus as target species and with Elaeagnus umbellate, Robinia pseudoacacia, Rhamnus cathartica, and Acer planoides as invasive species. Incorporating these links into the climate change framework developed by Davis et al. (2018) will create predictive models for the impacts of climate change on TER-S, which will affect land management decisions in the region.

28 Sep 2021

Corrosion and Performance of Dust Palliatives: Laboratory and Field Studies

Abstract: This report details laboratory and field experiments on BioPreferred® dust suppressants to assess performance and corrosion characteristics. Numerous bio-based dust suppressant products are marketed, but little data are available to assess performance for dust abatement and corrosion of common metals. A laboratory study used an air impingement device and the Portable In-Situ Wind ERosion Laboratory (PI-SWERL) to simulate wind speeds similar to those in field conditions for rotary wing aircraft. Laboratory corrosion studies used metal coupons imbedded in soil treated with dust palliative. Field trials were conducted using ground vehicle traffic to minimize cost and lower safety concerns while increasing surface wear from repetitive traffic. These studies clearly show that bio-based products demonstrate low corrosion potential with similar dust abatement performance to synthetic-based agents.

15 Jun 2021

Alternatives for Large Crater Repairs using Rapid Set Concrete Mix®

Abstract: Research was conducted at the U.S. Army Engineer Research and Development Center (ERDC) in Vicksburg, MS, to identify alternative repair methods and materials for large crater repairs using Rapid Set Concrete Mix®. This report presents the technical evaluation of the field performance of full-depth slab replacement methods conducted using Rapid Set Concrete Mix® over varying strength foundations. The performance of each large crater repair was determined by using a load cart representing one-half of the full gear of a C-17 aircraft. Results indicate that using rapid-setting concrete is a viable material for large crater repairs, and the performance is dependent on surface thickness and base strength.

12 May 2021

The Demonstration and Validation of a Linked Watershed-Riverine Modeling System for DoD Installations: User Guidance Report Version 2.0

Abstract: A linked watershed model was evaluated on three watersheds within the U.S.: (1) House Creek Watershed, Fort Hood, TX; (2) Calleguas Creek Watershed, Ventura County, CA; and (3) Patuxent River Watershed, MD. The goal of this demonstration study was to show the utility of such a model in addressing water quality issues facing DoD installations across a variety of climate zones. In performing the demonstration study, evaluations of model output with regards to accuracy, predictability and meeting regulatory drivers were completed. Data availability, level of modeling expertise, and costs for model setup, validation, scenario analysis, and maintenance were evaluated in order to inform installation managers on the time and cost investment needed to use a linked watershed modeling system. Final conclusions were that the system evaluated in this study would be useful for answering a variety of questions posed by installation managers and could be useful in developing management scenarios to better control pollutant runoff from installations.