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  • Morphology-Driven Electromagnetic Shielding Performance of Graphitic Nanoparticles in Segregated Polypropylene Nanocomposites via Electromagnetic Melt Processing

    Abstract: Electromagnetic melt-processing has emerged as an innovative and energy-efficient strategy for the structuring of thermoplastic nanocomposites. In this study, polypropylene (PP)-based TPNCs were fabricated using different grades of graphitic carbon nanoparticles to yield electrical conductivity and electromagnetic interference shielding effectiveness. The applied structuring methodology consists of a multiscale processing strategy that combines high-energy ball milling of polymer micro-pellets and CNPs, formulated powder compaction into green bodies, and EM-driven localized heating to produce the TPNCs. This enables the formation of highly segregated, percolated conductive networks at ultra-low filler loadings. The percolation threshold values for green bodies were significantly dependent on CNP morphology, ranging from approximately 0.50 wt% for low-aspect-ratio graphene nanoplatelets to around 1.0 wt% for medium-aspect-ratio carbon nanotubes. Upon EM melt-processing, due to viscoelastic deformation of CNP networks, the resulting threshold values of the structured TPNCs were approximately 0.73 wt%, 0.50 wt%, and 0.74 wt% for low, medium, and high aspect ratios, respectively. High-aspect-ratio CNTs, despite exhibiting greater structural defects, achieved the highest EMI SE of 19.7 dB/mm at 10 wt%, demonstrating that morphology dominates over graphitic crystallinity in governing transport properties and electromagnetic performance. Statistical modeling via response surface methodology confirmed the predictive significance of the CNP morphology and the concentration responses. This work underscores the critical influence of filler architecture and EM-induced structuring in enabling a novel, scalable platform for multifunctional polymer nanocomposites with enhanced electromagnetic shielding capabilities, offering promise for next-generation aerospace, electronics, automotive, and defense applications.
  • Standalone Color-Based Bathymetry Over 10 Years at Duck (NC, USA) from Optical Satellite Imagery and Wave Breaking Analysis

    Abstract: Coastal hazard forecasting and morphological modeling rely on having accurate and up-to-date nearshore bathymetry. Traditional methods provide high precision but are expensive, complex to deploy, and only cover limited areas, leaving many coastal regions unmapped or under surveyed. In this context, Satellite-Derived Bathymetry provides a more accessible and scalable alternative, enabling frequent and global observations of the nearshore zone. This study applies the color-based log-band ratio method to extract nearshore bathymetry at Duck, North Carolina, a highly dynamic environment with a wide range of turbidity values and wave breaking extents. The log-band ratio method is an empirical approach for estimating shallow-water depths from multispectral satellite imagery which relies on the natural attenuation of light in water column, where the ratio of two spectral bands is logarithmically related to water depth. Unlike traditional SDB approaches, this method relies only on nearshore in situ wave height data, using satellite-detected breaking positions and breaker height-to-depth ratio as depth calibration points. Additionally, an automated approach is used to select images where the green/blue band penetrates sufficiently into the water to retrieve bathymetry avoiding the subjectivity of traditional manual selection. The method is validated through alongshore median- and profile-based assessments, yielding a median RMSE of ∼60 cm. Sensitivity tests on key parameters, including the breaker height-to-depth ratio and the calibration time window, demonstrate that a constant breaker height-to-depth ratio provides reliable results and that a significant number of calibration points is necessary for accurate bathymetry retrieval. This approach retrieves instant bathymetries and allows for the extraction of bathymetry evolution over time, with 90 bathymetry maps available over the 10-year period due to the very high resolution and 2-day revisit VEN𝜇S satellite and the 10-m/5-day Sentinel-2 mission. The method is transferable to other optical satellites such as Landsat, although it should be applied with caution, enabling long-term nearshore bathymetry monitoring from the 1980s to the present.
  • Evaluating Freshwater Mussel Sampling Methodologies Using a Simulation Model

    Abstract: Field surveys form the basis of many research efforts and are the foundation for estimates of population size and density that inform conservation and management practices for imperiled species. As a result, evaluating the performance of different survey methods across a range of conditions that may be encountered in the field can increase understanding of the time and effort that may be required to ensure that survey results are sufficiently accurate and reliable for conservation goals. We used a spatially explicit agent-based model to simulate four commonly used freshwater mussel field survey methodologies: simple random sampling (SRS), transect random sampling (TRS), adaptive cluster sampling (ACS), and qualitative timed searches (QTS) to investigate the influence of sampling method, spatial distribution, and mussel density on the performance (i.e., accuracy, precision, and detection rate) of survey techniques. Our analysis suggests that mussel density, spatial distribution, and sampling effort influence sampling accuracy, precision, and species detection for all sampling methods. QTS produces highly variable catch-per-unit-effort (CPUE) metrics when mussels are dense and/or clustered, indicating the technique may be unreliable as a proxy for density. Quantitative methods like SRS and TRS may be well-suited for estimating population characteristics, but a high level of effort may be needed to obtain reasonable accuracy when mussels occur at low densities. ACS may be more efficient for mussels at low densities, but it can be challenging to plan for the level of effort required to complete an ACS protocol. Designing an ecological survey requires careful consideration of research objectives and available resources. Future research may consider the performance of qualitative and quantitative surveys in combination as a means of overcoming some of the practical challenges of applying individual survey methods.
  • Numerical Study of Submergence-Induced Forces on a Maintenance Bridge

    Abstract: The US Army Engineer Research and Development Center–Coastal and Hydraulics Laboratory conducted a numerical study for a proposed maintenance bridge over the Trinity River in downtown Fort Worth, Texas, that will be submerged in flood conditions. The purpose of this study was to determine the hydrodynamic loads on the structure. The study found that, due to a combination of peak velocities and water depth, a return period of 500 yr generates the largest drag forces, while the higher depth and discharge of the standard project flood generate larger lift forces. Two flow structures were observed with shallow submergence: The first resulted in a jet parallel to the deck with a recirculation extending from railing to railing and the second resulted in a plunging jet over the deck with smaller but stronger recirculation. These patterns resulted in significantly different loads on the structure. The study analyzed the bridge’s deck slope to the flow as a possible variable affecting the loads. Observed changes related mostly to the flow pattern predicted for different flow configurations. Finally, it was observed that an open railing provides the best possible conditions in terms of loading; therefore, minimizing the frontal area of the railing is recommended.
  • Investigation of Graphene Nanoplatelets for Adsorptive Removal of Aqueous Munitions Compounds 2,4,6-Trinitrotoluene (TNT) and Hexahydro-1,3,5-Trinitro-S-Triazine (RDX)

    Abstract: Graphene nanoplatelets (GnPs) were evaluated against munitions compounds 2,4,6-trinitrotoluene (TNT) and hexahydro-1,3,5-trinitro-s-triazine (RDX) in aqueous solutions for adsorptive removal performance. Fourier transform infrared and Raman spectroscopy were employed to characterize samples and inform adsorption mechanisms. Adsorption kinetics and isotherm studies were conducted in deionized water and compared with granular activated carbon (GAC). Evaluations were conducted with varying pH levels, ionic strengths, and temperatures and with surface water solutions to assess the impact of environmental factors on performance and further inform adsorption mechanisms. This study demonstrated that GnPs exhibited more rapid adsorption than GAC. Furthermore, TNT was adsorbed with greater capacity by GnPs compared to GAC, while GnPs removed RDX in greater capacity only when results were normalized for surface area. The more planar structure of GnPs may have contributed to performance enhancements relative to GAC. Adsorption was not impacted by variations in pH or ionic strength, indicating stable performance in different environments. Thermodynamic analysis indicated that removal was more favorable at higher temperatures. Furthermore, π-π interactions likely facilitated TNT removal by GnPs, while RDX was removed through physisorption by van der Waals forces. This study advanced understanding of environmental management of munitions compounds, as the adsorptive performance of GnPs for munitions compounds in solutions within a natural environmental matrix were evaluated, and key mechanisms supporting adsorptive removal of these compounds were informed. Overall, this study demonstrated the effectiveness of GnPs in treating water contaminated with TNT or RDX, particularly when rapid adsorption is preferred.
  • Mechanical Properties and Microstructure of Annealed Ni/CrC-NiCr Metal Matrix Composite Prepared by Cold Sprayed Deposition

    Abstract: This study investigates the effects of low (700 ◦C) and high (1000 ◦C) temperature annealing on the micro-structure and mechanical properties of two metal matrix composites consisting of Ni and two separate compositions of CrC-NiCr cold-sprayed onto A-514 structure steel. The mechanical properties, including tensile strength, ductility, interface shear strength, and microhardness, were evaluated after heat treatments. Additionally, scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD), and transmission electron microscopy (TEM) were used to characterize the microstructure of the annealed deposits. The results showed that annealing significantly enhanced the inter-splat bonding quality between the matrix (nickel) particles. However, higher temperature annealing led to an increase in voids surrounding the cermet particle due to enhanced elemental diffusion. Furthermore, the interparticle bonding between the nickel particles in the matrix and the cermet particle was also improved after annealing. Depending on the composition, the ultimate tensile strength increased by a minimum of 32 %, and the adhesion shear strength improved by over 77 % following annealing at 1000 ◦C. Recrystallization and reduction of the dislocation density in the nickel matrix occurred within the splats during annealing, resulting in increased ductility from less than 0.2 % in the as sprayed condition to more than 6.5 % after annealing. However, a general reduction in hardness was observed after annealing. The interplay between the annealing temperature, microstructural evolution, and mechanical performance demonstrates that the improved bonding directly influenced the mechanical properties, resulting in increased tensile strength, greater ductility, and a shift from brittle to ductile fracture behavior as the micro-structure evolved.
  • The Acoustic-Doppler Current Profiler (ADCP): A Comprehensive Tool for River Hydromorphodynamics Monitoring

    Abstract: This paper introduces the use of acoustic Doppler current profiler (ADCP) measurements as input for the Acoustic Mapping Velocimetry (AMV) method, a technique for characterizing the dynamics of riverine bedforms. The performance of this new approach, ADCP-AMV, is compared with input from a multibeam echosounder through a field study conducted on the Mississippi River (USA). A virtual ADCP tool has been created to support the ADCP-AMV measurements with optimal data density predictions. To the authors’ knowledge, this is the first time ADCP measurements have been used in conjunction with the AMV dune-tracking method. Subsequently, the paper discusses the coupling of ADCP-AMV measurements with ancillary data extracted from the ADCP. These ancillary data are processed using previously developed protocols to characterize hydrodynamics and the suspended sediment distribution in the water column. This paper emphasizes the capability of ADCPs to characterize open-channel river hydromorphodynamic parameters with high spatiotemporal resolution. Recommendations to accurately and efficiently acquire these multi-variable measurements and derived datasets are discussed.
  • Growth Patterns of Three Hydrilla Verticillata Biotypes in the United States

    Abstract: Hydrilla [Hydrilla verticillata (L.f. Royle)] is an invasive submersed plant first documented in the United States (US) in the 1950s. Until recently, only two distinct strains of hydrilla, hereafter referred to as biotypes, were recorded in the US with both belonging to the same clade and characterized as either ‘monoecious’ or ‘dioecious’. In 2016, a third genetically distinct biotype (‘clade C’) was identified in the lower Connecticut River, Connecticut. Trials were conducted at two geographically unique locations within North Carolina to compare growth and reproduction of hydrilla biotypes by climatic conditions. Nominal differences were observed in peak aboveground biomass, relative growth rate, or occurrence of these metrics among the three hydrilla biotypes, although the predicted peak biomass for dioecious hydrilla did not occur during the study period. Monoecious hydrilla exhibited lower peak belowground biomass than dioecious and clade C hydrilla despite its abundant subterranean turion production. Monoecious hydrilla exhibited 1.8X greater aboveground biomass 180 days after planting (Julian day 304) than clade C hydrilla. Clade C hydrilla produced 74 axillary turions per plant on Julian day 304, which equates to a 2.3X increase over monoecious hydrilla and 61.5X increase over dioecious hydrilla. Conversely, subterranean turion production was 4.7 and 7.1X higher in monoecious hydrilla and dioecious hydrilla than clade C hydrilla, respectively. These studies suggest the clade C hydrilla displays many phenological similarities to the other two biotypes in the US, but its prodigious axillary turion production poses concerning implications for potential to spread and persistence following management.
  • Assessing Relative Wetland Flood Risk Management Benefits Using COPE: An Exploration of Capacity, Opportunity, Payoff, and Efficacy

    Abstract: Wetlands reduce flood risk, but measuring their performance and benefits is challenging due to the highly variable nature of the factors, including landscape features, land use, and climate, that shape flood response. An evidence-based index was developed to rapidly assess the potential flood risk management benefits of wetland restoration. These benefits are measured by combining the Capacity (C), Opportunity (O), Payoff (P), and Efficacy (E) indicators into a single index, called COPE. Capacity captures the internal wetland characteristics that alter flood peak attenuation potential. Opportunity reflects watershed characteristics that control the effectiveness of internal wetland capacities. Payoff quantifies the population exposed to high flood risk, and Efficacy reflects the ability of communities to respond to flooding. Literature evidence for the C and O indicators suggests that flood risk is reduced by increasing wetland storage in small basins with hillslopes or in moderate to large riverine basins. Literature evidence for the E index suggests that multiple indicators can capture the potential for disproportionate harm to vulnerable communities. A case study demonstrated that the P indicator strongly influences the relative-benefits score produced by COPE, but the C, O, and E indexes can alter the score substantially when values deviate from average conditions.
  • Oyster Reef Ecosystem Recovery Monitoring: A Habitat Case Study for the US Army Corps of Engineers Aquatic Restoration Monitoring for Ecosystem Recovery (ARMER) Network

    Abstract: Oyster reefs are native to oceanic coasts of the contiguous United States, are great contributors to secondary production in estuaries, and provide food and other services to humans. Unfortunately, oyster reefs have become functionally extinct throughout much of their historical range due to overharvesting, disease, poor water quality, and weather-related drivers. Restoration efforts are underway in response to these population collapses and seek to replenish oyster populations to a level sustainable for ecosystem services. To evaluate effectiveness of these restoration interventions and characterize oyster reef recovery status on large scales, coordinated monitoring is needed to facilitate long-term collection, storage, and dissemination of data. The US Army Corps of Engineers has proposed the development of the Aquatic Restoration Monitoring for Ecosystem Recovery (ARMER) Network, a monitoring system composed of nationwide restoration and reference sites, to generate high-quality, replicated datasets to address large-scale ecosystem restoration challenges. This report details a framework of recovery attributes and associated monitoring metrics and methods proposed to characterize oyster reef habitat recovery following ecosystem restoration interventions. Monitoring recommendations, as well as existing monitoring networks and communities of practice, are discussed as key potential facets and partners in the operationalization of ARMER.