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Archive: 2025
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  • Carbon Nanotube-Based Segregated Thermoplastic Nanocomposites Structured via Electromagnetic Melt Processing

    Abstract: The EM-processed TPNCs prepared with EM-susceptible carbon nanotubes exhibited a significant enhancement in transport and mechanical properties, outperforming conventionally processed TPNCs. Thus, EM-processed TPNCs demonstrated an ultralow electrical percolation threshold and a remarkable increase in volume electrical conductivity of 8 orders of magnitude at only 1.0 wt % CNT loading. This highlights the superior network formation, level of segregation, and structuring enabled by EM processing. Differential scanning calorimetry and X-ray diffraction revealed EM-processed TPNCs exhibited higher crystallinity and a predominantly α crystal phase compared to hot-pressed TPNCs. Microstructural inspection by electron microscopy disclosed EM processing led to segregated but interconnected multiscale networks of a thin and well-defined CNT interphase that encompassed from the nanoscale of CNTs to the macroscopic scale of TPNCs. The EM-processed TPNCs developed a statistically higher stiffness and in certain cases, even better strength than hot-pressed TPNCs. However, EM-processed TPNCs displayed significantly lower ductility, owing to their higher crystallinity, more brittle crystal α phase, and potential formation of microvoids in the bulk of the TPNCs inherent to the unoptimized EM processing. This work provides an understanding of an alternative and unconventional processing method capable of achieving higher structuring in nanocomposites with advanced multifunctional properties.
  • Acoustic Winter Terrain Classification for Offroad Autonomous Vehicles

    Abstract: Autonomous vehicles can experience extreme changes in performance when operating over winter surfaces, and require accurate classification to transit them safely. In this work we consider acoustic classification of winter terrain, and demonstrate that a simple and efficient frequency-space analysis exposed to a small convolutional neural network, rather than recurrent architectures or temporally-varying spectrogram inputs, is sufficient to provide near-perfect classification of deep snow, hardpacked surfaces and ice. Using a dual-microphone configuration, we also show that acoustic classification performance is due to a combination of vehicle noises and vehicle-terrain interaction noises, and that engine sounds can serve as a particularly powerful classification cue for offroad environments.
  • Evaluating and Improving Snow in the National Water Model, Using Observations from the New York State Mesonet

    Abstract: This study leverages observations from NYSM to evaluate and improve representation of snow within the NWM and its associated land surface model. Distributed NWM simulations were ran and analyzed, forced by gridded meteorological analyses, and Noah-MP point simulations, forced by NYSM observations. Distributed NWM runs, with a baseline configuration, show substantial SWE biases caused by biases in meteorological forcing used, imperfect representation of snow processes, and mismatches between land cover in the model and NYSM station locations. Noah-MP point simulations, using baseline configuration, reveal a systematic positive bias in SWE accumulation. Noah-MP point simulations, with improved precipitation phase partitioning, reveal a systematic negative bias in SWE ablation rates. Sensitivity experiments highlight uncertain parameters within Noah-MP that strongly affect ablation rates and show particularly large sensitivity to snow albedo decay time-scale parameter, which modulates snow albedo decay rates. Distributed NWM experiments, with precipitation phase partitioning and TAU0 adjusted based on Noah-MP point simulation results, show qualitatively similar sensitivities. However, the distributed experiments do not show clear improvements when compared to SWE and streamflow observations. This is likely due to some combination of sources of bias in the baseline-distributed run and biases in other parameterized processes unrelated to snow in the NWM.
  • Cracking Performance Characterisation of Aramid Fiber-Reinforced Asphalt Mixtures Using Digital Image Correlation

    Abstract: Conventional index-based testing of asphalt mixtures cannot accurately capture local deformation in a sample, limiting the usage of standard test measurements. The non-contact-based measurements proved effective to capture local deformation fields. This study aimed to capture the fatigue and thermal cracking behaviour of fiber-reinforced asphalt mixture by utilising digital image correlation (DIC). One binder (PG76-22), a diabase aggregate and three fibers (polyolefin/ aramid fibers (PFA) at 0.05% dosage and Sasobit-coated aramid fibers at 0.01% and 0.02% dosage) were used to prepare a total of four mixtures (one control and three FRAM). All these mixtures were produced at a local batch plant following manufacturer-recommended mixing methods. DIC analysis was performed for three-point bending beam (3PB) and disk shape compact tension (DCT) tests at intermediate temperature (25°C) and low temperatures of −12°C and −18°C. Based on index values from DCT and 3PB, the thermal and fatigue cracking performance enhancement was not significant. However, DIC analysis showed that, regardless of testing temperature, the crack propagated in a random pattern for FRAM, whereas the crack followed a relatively straight path for the control mix. Finally, based on DIC strain contours, FRAM mixtures exhibit distributed strain over a larger area compared to the control mix.
  • 3D Printing of Ultra-High-Performance Concrete: Shape Stability for Various Printing Systems

    Abstract: Attention is on concrete 3D printing for its potential in structure optimization, life-cycle extension, emission reduction, and cost savings. Previous studies tailor a mix to a specific printing system and evaluate printability based on measurements of pumpability, extrudability, and buildability. For this investigation, an experimental program was conducted using various printing systems on a nano-modified UHPC mix. A medium-scale gantry and a large-scale ABB robotic arm were utilized, piston-type extruder and an auger system were employed, various nozzles, including circular and rectangular designs, were tested, and a cavity and Thom-Katt pump were used. Results indicated the shape stability of the UHPC mix is influenced by the printing system. Furthermore, the use of a circular nozzle demonstrated different shape stabilities when the extrusion system was changed from a piston-type extruder to an auger system. Additionally, the method of material pumping to the extrusion system was found to be critical for shape stability of printed layers. The mix failed to maintain its shape post-extrusion when using the cavity pump, which was attributed to higher strain rates imposed on material during the pumping process. This issue was not observed when the piston-type pump was used.
  • C-Band Radar Measurements in a Snow-Covered Boreal Forest Environment

    Abstract: Sled-based side-looking C-band radar profiles were collected around Fairbanks, Alaska, in March 2023 during the NASA SnowEx campaign to improve the conceptual understanding of C-band radar wave interactions with snow in a boreal forest environment. Seven transects with different vegetation and ground conditions were studied. Significant volume scattering from snow was observed in this shallow snowpack, indicating sensitivity at lower snow depths (SDs) which are common in high-latitude snowpacks. Manual removal of the snowpack decreased the backscatter by more than 2 dB in all polarizations, with a larger decrease in the cross-polarization, supporting the potential use of Sentinel-1 to retrieve SD.
  • Financing Natural Infrastructure: Lightning Point, Alabama

    Purpose: This technical note explores the restoration of Lightning Point, an award-winning natural infrastructure project led by The Nature Conservancy (TNC) in coastal Alabama. The story of Lightning Point provides an exemplar case study of successful coordination of cross-sector partnerships and the use of ecosystem services valuation to attract project funding.
  • Continued Development of Methods for the Determination of Legacy and Insensitive Munitions from Environmental Matrices: Addition of Four Degradation Products and One Internal Standard to Previously Developed 29-Analyte Method

    Abstract: To continue improving separation methods of explosive analytes and their degradation products, chromatographic methods from Environmental Protection Agency (EPA) 8330B, Strategic Environmental Research and Development Program (SERDP) 2722, and Environmental Sensors for Explosives were modified to include the separation of four additional analytes and one internal standard so that a total of 36 analytes could be resolved on a single column. Four degradation compounds, 3-amino-1,2,4-triazol-5-one (ATO); 1 methyl-3-nitroguandine (MeNQ); 2 methoxy-5-nitroaniline (MENA); and 4 methoxy-3-nitroaniline (iMENA) were added to the analytical method. The internal standard, 3,5-dinitrotoluene, was also added to the method to extend its application. Additionally, an analytical method on gas chromatography (GC) and gas chromatography–mass spectrometry (GC-MS) were explored for the analytes of interest.
  • Thermodynamic Exposure Reductions of PCBs Available to Lumbriculus variegatus in Lake Erie Region Sediments Amended with Activated Carbon

    Abstract: A chemical activity-based assessment of PCB bioaccumulation from Lake Erie region sediments was studied using polydimethylsiloxane coated fibers and Dow Corning silicone coated jars. Polymers equilibrated with the sediments were compared to bioaccumulation in blackworms, exposed to the sediments for 28 days. Sediments were from Cleveland Harbor, Ashtabula Harbor, and Buffalo River. Sediment from Ashtabula was amended with activated carbon. Using lipid-polymer partition coefficients, the polymers were able to estimate actual bioaccumulation in worms, with close to a 1:1 relationship and r2 = 0.94. If lipid normalized worm bioaccumulation was compared to equilibrated PDMS concentrations, there was a 20:1 ‘off-set,’ but the relation was still strong. Different doses of AC were mixed into Ashtabula sediment in the laboratory, corresponding to 1 %, 10 %, and 100 % of the native total organic carbon. Based on PCB concentrations in DC silicone, a target AC dose equal to 10 % of the TOC would substantially reduce bioaccumulation of the more hydrophobic PCBs from Ashtabula Harbor dredged material. Widespread AC amendment to surficial sediment of the eastern basin of Lake Erie may reduce the thermodynamic pressure of PCBs from that sediment source and allow for a continued decline in fish tissue concentrations.
  • Vessel Draft and Velocity Updates for Tybee Island Vessel Wake Analysis

    Purpose: This Coastal and Hydraulics Engineering technical note (CHETN) updates the results of a previous study (ERDC/CHL TR-22-21; Bain et al. 2022) and evaluates whether newly available datasets offer greater insight into the relationship between vessel characteristics and wake conditions near Tybee Island, Georgia. Whereas the original study used vessel drafts from the Automatic Identification System (AIS), the present analysis substitutes more accurate draft information from US Customs Foreign Vessel Entrances and Clearances (FVEC) records. In addition, cross-sectionally averaged flow velocities from the US Geological Survey (USGS) gauge at Fort Pulaski, Georgia, are used to update the AIS-reported speed over ground (SOG), yielding the vessels’ speed relative to the water. The combination of these two updates generates a visible improvement in wake forecasting ability. However, the mechanisms underlying drawdown oversteepening and bore formation near the beach remain poorly understood, and further study is recommended to determine the cause of this hazardous behavior.