29 Aug 2025

Nanofiber Fabrication by Electrospinning Technology: Optimization, Characterization, and Application

Abstract: This project explores electrospinning (ES) as one of the most successful technologies to produce nanofiber materials. Electrospun nanofibers are used in various military technologies, including advanced filtration systems, impact-resistant protective gear, thermal insulation, radar absorption for camouflage and stealth, antimicrobial wound dressings, drug-delivery patches, rapid healing, efficient solar cells, and self-cleaning materials for regeneration. Researchers at the US Army Engineer Research and Development Center (ERDC) investigated electrospinning effects on morphology, crystallinity and distribution of metal oxides for photocatalytic activities, and magnetic and mechanical properties in reinforcing composites. This study includes the following fabricated electrospun mats: -iron and titanium oxide (Fe3O4 and TiO2) with polyvinyl alcohol (PVA) -graphene, graphene oxide, and reduced graphene oxide with polyvinylidene fluoride (PVDF) -graphene-polyacrylonitrile (PAN) -metal-organic frameworks (MOF), graphene-MXene with PAN The research presented herein includes electrospinning theory, process, and parameters; sol–gel technology in solution preparation; and electrospinning sample characterization to guide readers in the fabrication of electrospun fibers with targeted characteristics. Future studies explore electrospun MOFs and MXene, a class of two-dimensional inorganic compounds with transition metal carbides, nitrides, or carbonitrides composites. These studies are invaluable for advancing military programs and enhancing warfighter support and civil works.

19 Aug 2025

Cooperative Molecular Interaction-Based Highly Efficient Capturing of Ultrashort- and Short-Chain Emerging Per- and Polyfluoroalkyl Substances Using Multifunctional Nanoadsorbents

Abstract: The short-chain and ultrashort-chain per- and polyfluoroalkyl substances are bioaccumulative, carcinogenic to humans, and harder to remove using current technologies. Herein, we report the development of nonafluorobutane-sulfonyl and polyethylene-imine -conjugated Fe3O4 magnetic nanoparticle-based magnetic nanoadsorbents and demonstrated the novel adsorbent has the capability for highly efficient removal of six different short- and ultrashort-chain PFAS from drinking and environmental water samples. Reported experimental data indicates by capitalizing the cooperative hydrophobic, fluorophilic, and electrostatic interaction processes, NFBS-PEI-conjugated magnetic nanoadsorbents can remove ~100% short-chain perfluorobutanesulfonic acid within 30 min from the water sample with a maximum absorption capacity qm of ~234 mg g−1. Furthermore, to show how cooperative interactions are necessary for effective capturing of ultrashort and short PFAS, a comparative study has been performed using PEI-attached magnetic nanoadsorbents without NFBS and acid-functionalized magnetic nanoadsorbents without PEI and NFBS. Reported data show the ultrashort-chain perfluoropropanesulfonic acid capture efficiency is the highest for the NFBS-PEI-attached nanoadsorbent. Moreover, reported data demonstrate that nanoadsorbents can be used for effective removal of short-chain PFAS and ultrashort-chain PFAS simultaneously from reservoir, lake, tape, and river water samples within 30 min, which shows the potential of nanoadsorbents for real-life PFAS remediation.

15 Apr 2025

Resilience and Efficiency for the Nanotechnology Supply Chains Underpinning COVID-19 Vaccine Development

Abstract: Nanotechnology facilitated the development and scalable commercialization of many SARS-CoV-2 vaccines. However, the supply chains underpinning vaccine manufacturing have demonstrated brittleness at various stages of development and distribution. Whereas such brittleness leaves the broader pharmacological supply chain vulnerable to significant and unacceptable disruption, strategies for supply chain resilience are being considered across government, academia, and industry. How such resilience is understood and parameterized, however, is contentious. Our review of the nanotechnology supply chain resilience literature, synthesized with the larger supply chain resilience literature, analyzes current trends in implementing and modeling resilience and recommendations for bridging the gap in the lack of quantitative models, consistent definitions, and trade-off analyses for nano supply chains.

13 Mar 2023

Safe and Rapid Development of Advanced Materials: A Research Case Study for Safe Development of Nanoenabled Environmental Sensors

Abstract: The enhanced understanding of nanomaterials properties and processing has led to increased use of nanotechnologies, which has also led to greater scrutiny on the commercialization and acquisition of emerging nanoenabled technologies. Caused by knowledge gaps on the unique behaviors, risks, and liabilities of novel engineered nanomaterials, this caution, when not evidence based, slows production and stifles innovation. Reducing the uncertainty surrounding the environmental risks and benefits of nanoenabled technologies, including their resilience in harsh environments, will speed the development and transition of advanced material technologies. In this work, a multifaceted research program generated data and processes to reduce that environmental uncertainty. Specifically, this case study examined printed, nanoenabled environmental sensors and their components to develop toxicological data and parameterize a life-cycle assessment. The study tested the sensors’ resilience in environmental weathering studies that considered both the potential release of the ingredient nanomaterials and the performance of the sensors after exposure to several harsh environmental climates and then created life-cycle inventories to determine environmental impact and reduce cost of research and development. Finally, this case study developed software tools to mitigate the cost of research and provide a framework for presenting toxicology data.