13 Apr 2026

Review of Emerging and Nonconventional Analytical Techniques for Per- and Polyfluoroalkyl Substances (PFAS): Application for Risk Assessment

Abstract: Per- and polyfluoroalkyl substances (PFAS) are persistent environmental contaminants that pose significant risks to ecosystems and human health. Increasing regulatory demands for PFAS management have increased the need for rapid and deployable analytical technologies for both abiotic and biotic matrices. Traditional detection methods, such as standardized chromatography, often require weeks to months for analysis due to a limited number of appropriately accredited laboratories, delaying critical decision-making. This literature review is intended to identify promising emerging PFAS analytical techniques or technologies to facilitate more rapid (near real-time) analysis and explore their relevancy in supporting human and ecological risk assessments. Recently developed optical and electrochemical sensing approaches are enabling the detection of PFASs within minutes to hours, with detection limits typically aligning within reported ambient concentrations in water, soil, and sediment. These emerging technologies could (1) support planning and prioritization of sampling efforts during the problem formulation phase of risk assessment, (2) complement traditional chromatography methods to lower time and resource demands to improve sampling frequency over space and time, and (3) aid in risk-informed characterization of PFAS exposures based on identified chemical classes or groups. This review highlights those approaches and technologies that could potentially enhance the comprehensiveness and efficiency of PFAS risk assessment across diverse environmental settings in the future.

23 Mar 2026

Assessment of Aluminum-Based Drinking Water Treatment Residuals from Multiple Utilities in the United States as Green Sorbents for PFAS

Abstract: Per- and polyfluoroalkyl substances are persistent environmental contaminants causing human health concerns. In this study, five aluminum-based drinking water treatment residuals were evaluated as green adsorbents for the removal of perfluorooctanoic acid and perfluorooctanesulfonic acid from water. Al-WTRs are nonhazardous solid wastes generated during the coagulation process of water treatment using aluminum salts or polymers. Although high PFAS adsorption capacity of Al-WTRs generated in one facility in the US has been reported, no study exists assessing PFAS adsorption capabilities of WTRs generated in multiple facilities using various types of aluminum coagulants. Batch adsorption experiments of PFOA and PFOS on Al-WTRs showed removal efficiencies exceeding 70 % for PFOA and 94 % for PFOS across all Al-WTRs. Maximum adsorption capacities for PFOS were significantly higher than those for PFOA, indicating the stronger affinity of the Al-WTRs for PFOS. Low desorption rates for both PFOA and PFOS suggested irreversible adsorption. Correlation analysis revealed that oxalate-extractable Al, Fe, and organic matter primarily contributed to PFOA adsorption, while pore size, oxalate-extractable Al, Fe, and total calcium primarily contributed to PFOS adsorption. These easily measurable parameters could be used as predictors when utilizing Al-WTRs as sustainable sorbents for PFAS removal. This study not only establishes the comparative and predictive performance of Al-WTRs from multiple utilities for PFAS sorption but also demonstrates their recycling potential within a circular-economy framework.

26 Feb 2025

Demonstration of Photocatalytic Degradation of Per- and Polyfluoroalkyl Substances (PFAS) in Landfill Leachate Using 3D Printed TiO2 Composite Tiles

Abstract: Per- and polyfluoroalkyl substances (PFAS) are recalcitrant substances present globally in many landfill wastewater leachates and have potential ecological and human health risks. Conventional treatment technologies have shown limited efficacy for many PFAS due to the stable C–F bonds. Therefore, there is growing interest in applying advanced oxidation processes to decrease the aqueous concentrations in contaminated wastewater and mitigate risks. The goal of this study was to evaluate the photocatalytic performance of treating PFAS in landfill leachate using a novel photocatalyst composite. Treatment structures were fabricated using polylactic acid and compounded with TiO2, and 3D printed into tiles. A pilot-scale treatment system was designed to promote photocatalysis using 3D composite structures and UV irradiance intensity of 1.0 mW cm−2 following 24- and 36-h hydraulic retention times. Photocatalytic degradation was achieved for seven of the 11 PFAS evaluated in this study. Greater than 80% removal of PFOS, PFNA, PFDA, and PFOSAm was observed after 24 h of photocatalysis. These results indicate photocatalysis using TiO2 polymer composites can achieve beneficial levels of PFAS degradation. This study provides a proof-of-principle approach to inform the application of additive manufacturing of photocatalytic composites for use in the treatment of PFAS-contaminated wastewater.