7 Mar 2025

Coupling Electrokinetics and Phytoremediation to Remove Uranium from Contaminated Soil: A Laboratory Pilot-Scale Study

Abstract: Uranium is a naturally occurring trace element and radionuclide. Uranium is introduced to the environment anthropogenically because of industrial, military, and nuclear energy activities. The approach of coupled electrokinetic phytoremediation has been used to remove other heavy metals from contaminated soil. The objectives here are to investigate the distribution and solubility of uranium in soils with UO2, UO, and uranyl, and examine the processes of coupled electrokinetic phytoremediation in removing U from soils with perennial ryegrass at a laboratory pilot scale. A low-intensity direct electric current field was applied to the contaminated soil for 7 d at 8 h·d−1 after ryegrass was grown for 2 weeks, then, polarity reversal was employed for another 7 d at 8 h·d−1. The uranium redistribution took place among various solid-phase components due to changes in the pH and chemistry of the electrolyte solution. The electrokinetic field increased the U bioavailability in soils as water-soluble U and exchangeable U in contaminated soils with all U species. Thus, the EKF significantly increased the U uptake and bioaccumulation by ryegrass. The current laboratory pilot-scale test confirmed our previous observation from the pot greenhouse study–the coupled electrokinetic phytoremediation may have potential for application in remediating U-contaminated sites.

1 Jul 2020

PUBLICATION NOTICE: Electrokinetic-Enhanced Phytoremediation of Uranium-contaminated Soil Using Sunflower and Indian Mustard

Abstract: Electrokinetic-enhanced phytoremediation is an effective technology to decontaminate heavy metal contaminated soil. In this study, we examined the effects of electrokinetic treatments on plant uptake and bioaccumulation of U from soils with various U sources. Redistribution of uranium in soils as affected by planting and electrokinetic treatments was investigated. The soil was spiked with 100mg kg⁻¹ UO₂, UO3, and UO₂(NO₃)₂. After sunflower and Indian mustard grew for 60 days, 1 voltage of direct-current was applied across the soils for 9 days. The results indicated that U uptake in both plants were significantly enhanced by electrokinetic treatments from soil with UO₃ and UO₂(NO₃)₂. U was more accumulated in roots than in shoots. Electrokinetic treatments were effective on lowering soil pH near the anode region. Overall, uranium (U) removal efficiency reached 3.4–4.3% from soils with UO₃ and uranyl with both plants while that from soil with UO₂ was 0.7–0.8%. Electrokinetic remediation treatment significantly enhanced the U removal efficiency (5–6%) from soils with UO₃ and uranyl but it was 0.8–1.3% from soil with UO₂, indicating significant effects of U species and electrokinetic enhancement on U bioaccumulation. This study implies the potential feasibility of electrokinetic-enhanced phytoremediation of U soils with sunflower and Indian mustard.

1 Jul 2020

PUBLICATION NOTICE: A Novel Laboratory Simulation System to Uncover the Mechanisms of Uranium Upward Transport in a Desert Landscape

Abstract: After depleted uranium (DU) is deposited in the environment, it corrodes producing mobile uranium species. The upward transport mechanism in a desert landscape is associated with the dissolution/precipitation of uranium minerals that vary in composition and solubility in soil pore water. The objective of this study is to develop the laboratory column simulation to investigate the upward transport mechanism with cyclic capillary wet-ting and drying moisture regimes. Results showed that evaporation driven upward transport occurred even during the first 2 months of wetting-drying regimes. Evaporation driven upward transport may control the U movement in the soil profile in an arid climate. The new system did not generate any uranium-containing wastewater. • Simulates the upward transport process of pollutants with different pollution levels and species. • Simultaneously simulate the transport process of multiple pollutants simultaneously. • Evaluate the influence of biogeochemical factors on pollutant transport such as various cations and anions (Ca, Mg and carbonates) in water.