18 Aug 2025

Coastal Environments: LiDAR Mapping of Copper Tailings Impacts, Particle Retention of Copper, Leaching, and Toxicity

Abstract: Tailings generated by mining account for the largest world-wide waste from industrial activities. Copper is relatively uncommon, with low concentrations in sediments and waters, yet is very elevated around mining operations. On the Keweenaw Peninsula, 140 mines extracted native copper from the Portage Lake Volcanic Series, part of an intercontinental rift system. Between 1901 and 1932, two mills at Gay sluiced 22.7 million metric tonnes of copper-rich tailings into Grand Traverse Bay. About 10 MMT formed a beach which migrated 7 km to the Traverse River Seawall. Another 11 MMT are moving underwater along the coastal shelf, threatening Buffalo Reef. Remote sensing techniques documented geospatial environmental impacts and initial phases of remediation. Aerial photos, ALS LiDAR/MSS surveys, and recent UAS overflights aid comprehensive mapping efforts. Because natural beach quartz and basalt stamp sands are silicates of similar size and density, percentage stamp sand determinations utilise microscopic procedures. Copper leaching is elevated by exposure to high DOC and low pH waters, characteristic of riparian environments. Lab and field toxicity experiments, plus benthic sampling, all confirm serious impacts of tailings on aquatic organisms. Mining companies should end coastal discharges and also adopt the UNEP “Global Tailings Management Standard for the Mining Industry”.

27 Mar 2024

Approach for On-Site, On-Demand Contaminant-Removal Devices Enabled by Low-Cost 3D Printing

Purpose: The purpose of this technical note is to disseminate methods to design and create a 3D device that could be used to determine relative toxicity potential of existing and emerging contaminants of concern in situ for sediment shoaled in federal navigation channels prior to being dredged. This device has the potential to reduce the cost of conventional sediment evaluations conducted prior to dredging operations.

21 Sep 2021

Identifying Degradation Products Responsible for Increased Toxicity of UV-Degraded Insensitive Munitions

Abstract: Degradation of insensitive munitions (IMs) by ultraviolet (UV) light has become a concern following observations that some UV-degradation products have increased toxicity relative to parent compounds in aquatic organisms. This investigation focused on the Army's IM formulation, IMX101, composed of three IM constituents: 2,4-dinitroanisole (DNAN), 3-nitro-1,2,4-triazol-5-one (NTO), and nitroguanidine (NQ). The IM constituents and IMX101 were irradiated in a UV photo-reactor and then administered to Daphnia pulex in acute (48 h) exposures comparing toxicities relative to the parent materials. UV-degradation of DNAN had little effect on mortality whereas mortality for UV-degraded NTO and NQ increased by factors of 40.3 and 1240, making UV-degraded NQ the principle driver of toxicity when IMX101 is UV-degraded. Toxicity investigations for specific products formed during UV-degradation of NQ, confirmed greater toxicity than the parent NQ for degradation products. Summation of the individual toxic units for the complete set of individually measured UV-degradation products identified for NQ only accounted for 25% of the overall toxicity measured in the exposures to the UV-degraded NQ product mixture. Given the underestimation of toxicity using the sum toxic units for the individually measured UV-degradation products of NQ, we conclude that: (1) other unidentified NQ degradation products contributed principally to toxicity and/or (2) synergistic toxicological interactions occurred among the NQ degradation product mixture that exacerbated toxicity.