4 May 2026

Insight into the Photocatalytic Degradation Mechanism for “Forever Chemicals” PFNA by Reduced Graphene Oxide/WO3 Nanoflower Heterostructures

Abstract: Water contamination with “forever chemicals” like per- and polyfluoroalkyl substances (PFAS) poses significant toxicity to the environment. Since they are the most persistent synthetic chemicals that hardly degrade in the natural environment and are carcinogenic to humans, there is an urgent need to discover novel processes for destroying PFAS. Herein, we report on the design of a reduced graphene oxide (r-GO)/WO3 nanoflower (WO3-NF)-based heterostructure for harnessing 365 nm light-driven photocatalytic oxidation and reduction process toward the photocatalytic degradation of perfluorononanoic acid (PFNA). Moreover, reported data reveal that using an r-GO/WO3-NF heterostructure photocatalyst, 100% PFNA degradation and 14% defluorination can be achieved in the presence of isopropyl alcohol as the hydroxy radical (•OH) quencher or glucose as a hot hole (h+) quencher after exposure to 365 nm light for 22 h. A reported mechanistic study shows synergistic oxidation and reduction processes are vital for the complete degradation of PFNA, where the hydrated electron (eaq−) plays a key role as a reducing agent and h+ and •OH act as oxidation agents. Furthermore, the photocatalytic destruction mechanism study indicates that chain shortening via C−C bond breaking and defluorination via C−F bond breaking are major pathways for PFNA degradation. A wavelength-dependent study shows that only 22% degradation can be achieved after exposure to 532 nm light for 22 h, which is due to the lack of the formation of hydrated electrons (eaq−). The current study sheds light on the construction of the r-GO/WO3 NF heterojunction for the highly efficient degradation of PFAS.

3 Mar 2026

Overview of PFAS in Aquatic Environments

Abstract: PFAS are highly stable fluorinated compounds with unique properties and are used in a broad array of industrial processes and commercial products. PFAS are extremely recalcitrant and are widespread in the environment, with measurable concentrations in soils, sediments, groundwater, surface water, and rainwater, even at sites far removed from known sources or releases. Select PFAS (especially longer-chain perfluorinated carboxylic and sulfonic acids) are known to bioaccumulate in aquatic food webs, presenting potential risk to higher trophic species, including hu-mans. Evidence suggests sediment serves as a repository and potential ongoing source for many of these long-chain PFAS. The global presence and persistence of PFAS pose a fundamental challenge to addressing potential effects on environmental quality and health. The public and policymakers are increasingly concerned about the potential presence and effects of PFAS in water and sediments. This concern includes knowledge gaps for dredged material management, posing challenges to execution of the US Army Corps of Engineers Civil Works navigation program. This document provides a comprehensive review of PFAS in the aquatic environment based on published studies and includes overviews of chemical classifications, regulatory considerations, historical uses and sources, environmental distribution, fate and transport pathways, and uptake and effects in aquatic organisms.

20 Feb 2026

Demonstration Validation of Industrial Supercritical Water Oxidation (iSCWO) PFAS Destruction Technology: Aqueous Film-Forming Foam Treatment by General Atomics (GA) iSCWO System

Abstract: The Department of Defense (DoD) is confronted with a pressing environmental challenge concerning legacy aqueous film-forming foam (AFFF) concentrate, historically used in firefighting activities. Legacy AFFF contains PFAS, which are identified as persistent environmental contaminants associated with adverse health effects. Considering increasing environmental regulations and concerns regarding human health impacts, the DoD needs to properly destroy legacy AFFF. The US Army Engineer Research and Development Center (ERDC) led a project focused on the demonstration and validation of technologies for the destruction of PFAS in AFFF. Results are presented for the treatment of 100 gal. of AFFF using the General Atomics industrial Supercritical Water Oxidation system. The demonstration showed destruction removal efficiencies (DREs) for total PFAS analyzed via total oxidizable precursor (TOP) assay (S24 PFAS), ranging from 98.5% to 99.9991%. No volatile fluorinated compounds were detected in the stack emissions as analyzed via Other Test Method 50; however, up to 6,000 ppt S51 PFAS as analyzed via TOP assay was detected in demister effluent. The energy consumed per cubic meter of AFFF and order of magnitude S24 PFAS destroyed ranged from 2 to 24 MWh, while the energy consumed per gram of S24 PFAS destroyed ranged from 0.046 to 48 MWh.

19 Aug 2025

Cooperative Molecular Interaction-Based Highly Efficient Capturing of Ultrashort- and Short-Chain Emerging Per- and Polyfluoroalkyl Substances Using Multifunctional Nanoadsorbents

Abstract: The short-chain and ultrashort-chain per- and polyfluoroalkyl substances are bioaccumulative, carcinogenic to humans, and harder to remove using current technologies. Herein, we report the development of nonafluorobutane-sulfonyl and polyethylene-imine -conjugated Fe3O4 magnetic nanoparticle-based magnetic nanoadsorbents and demonstrated the novel adsorbent has the capability for highly efficient removal of six different short- and ultrashort-chain PFAS from drinking and environmental water samples. Reported experimental data indicates by capitalizing the cooperative hydrophobic, fluorophilic, and electrostatic interaction processes, NFBS-PEI-conjugated magnetic nanoadsorbents can remove ~100% short-chain perfluorobutanesulfonic acid within 30 min from the water sample with a maximum absorption capacity qm of ~234 mg g−1. Furthermore, to show how cooperative interactions are necessary for effective capturing of ultrashort and short PFAS, a comparative study has been performed using PEI-attached magnetic nanoadsorbents without NFBS and acid-functionalized magnetic nanoadsorbents without PEI and NFBS. Reported data show the ultrashort-chain perfluoropropanesulfonic acid capture efficiency is the highest for the NFBS-PEI-attached nanoadsorbent. Moreover, reported data demonstrate that nanoadsorbents can be used for effective removal of short-chain PFAS and ultrashort-chain PFAS simultaneously from reservoir, lake, tape, and river water samples within 30 min, which shows the potential of nanoadsorbents for real-life PFAS remediation.

14 May 2024

Properties and Mechanisms for PFAS Adsorption to Aqueous Clay and Humic Soil Components

Abstract: The proliferation of poly- and perfluorinated alkyl substances (PFASs) has resulted in global concerns over contamination and bioaccumulation. PFAS compounds tend to remain in the environment indefinitely, and research is needed to elucidate the ultimate fate of these molecules. We have investigated the model humic substance and model clay surfaces as a potential environmental sink for the adsorption and retention of three representative PFAS molecules with varying chain length and head groups. Utilizing molecular dynamics simulation, we quantify the ability of pyrophyllite and the humic substance to favorably adsorb these PFAS molecules from aqueous solution. We have observed that the hydrophobic nature of the pyrophyllite surface makes the material well suited for the sorption of medium- and long-tail PFAS moieties. Similarly, we find a preference for the formation of a monolayer on the surface for long-chain PFAS molecules at high concentration. Furthermore, we discussed trends in the adsorption mechanisms for the fate and transport of these compounds, as well as potential approaches for their environmental remediation.

22 Feb 2024

2D Fluorinated Graphene Oxide (FGO)-Polyethyleneimine (PEI) Based 3D Porous Nanoplatform for Effective Removal of Forever Toxic Chemicals, Pharmaceutical Toxins, and Waterborne Pathogens from Environmental Water Samples

Abstract: Although water is essential for life, as per the United Nations, around 2 billion people in this world lack access to safely managed drinking water services at home. Herein we report the development of a two-dimensional (2D) fluorinated graphene oxide (FGO) and polyethylenimine (PEI) based three-dimensional (3D) porous nanoplatform for the effective removal of polyfluoroalkyl substances (PFAS), pharmaceutical toxins, and waterborne pathogens from contaminated water. Experimental data show that the FGO-PEI based nanoplatform has an estimated adsorption capacity (qm) of ∼219 mg g−1 for perfluorononanoic acid (PFNA) and can be used for 99% removal of several short- and long-chain PFAS. A comparative PFNA capturing study using different types of nanoplatforms indicates that the qm value is in the order FGO-PEI > FGO > GO-PEI, which indicates that fluorophilic, electrostatic, and hydrophobic interactions play important roles for the removal of PFAS. Reported data show that the FGO-PEI based nanoplatform has a capability for 100% removal of moxifloxacin antibiotics with an estimated qm of ∼299 mg g−1. Furthermore, because the pore size of the nanoplatform is much smaller than the size of pathogens, it has a capability for 100% removal of Salmonella and Escherichia coli from water. Moreover, reported data show around 96% removal of PFAS, pharmaceutical toxins, and pathogens simultaneously from spiked river, lake, and tap water samples using the nanoplatform.

20 Nov 2023

Internal Standard and Deuterated Solvent Selection: A Crucial Step in PFAS-based Fluorine-19 (¹⁹F) NMR Research

Purpose: This work is vital because it provides researchers with a framework and rationale for selecting the best internal standard and deuterated solvent for their nuclear magnetic resonance (NMR) analysis of per- and polyfluoroalkyl substances (PFAS)-based compounds. Selecting the best internal standard and deuterated solvent will help to ensure that their results are accurate, precise, and sensitive. The internal standard that is chosen can significantly affect the accuracy, precision, sensitivity, and quantification of NMR measurements. Therefore, it is essential to carefully select an internal standard and a matching deuterated solvent that are well-suited for analyzing PFAS compounds.

31 May 2023

Extraction and Analysis of Per- and Polyfluoroalkyl Substances (PFAS) from Meals Ready-to-Eat (MRE) Films Using GC-MS and LC-MS/MS

OBJECTIVE: This work was in response to the Defense Logistic Agency’s (DLA) Subsistence Network Broad Agency Announcement, BAA-0003-16 addressing 2019 NDAA Section 329 that states packaging materials used for Meals Ready-to-Eat (MRE) that contact food products must be free of per- and polyfluoroalkyl substances (PFAS). This was addressed by determining the presence or absence of PFAS on MREs by extraction followed by gas chromatography mass spectrometry (GC-MS) and liquid chromatography tandem mass spectrometry (LC-MS/MS). Any samples positive for PFAS were quantitated using LC triple quadrupole (QqQ) MS at the US Army Engineering and Research Development Center (ERDC) and by high resolution quadrupole time-of-flight (qTOF) MS and GC-MS at Oregon State University (OSU).

1 Oct 2020

Optimization of LC-MS/MS Parameters for Analysis of Per- and Polyfluoroalkyl Substances (PFAS)

Purpose: Integrate US Environmental Protection Agency (USEPA) Method 537 on current instrumentation to provide per- and polyfluoroalkyl substances (PFAS) analytical capabilities for the US Army Engineer Research and Development Center (ERDC), US Army Corps of Engineers (USACE) and the Department of Defense (DoD).